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《Ceramics International》2020,46(10):15972-15981
ZrO2 toughened Al2O3 particles (ZTAp) have poor wettability with iron, and therefore some defects are easily formed at the interface between ZTAp and iron matrix, which may lead to material failure. This paper illustrates that the ZTAp were modified on the surface by the active Mo–Mn metallization, and thus, they were used as the reinforcing phases to prepare the iron-matrix composite (ZTAp/Fe composite). It is concluded that the sponge-like skeleton structure was formed on the surface of ZTAp after the metallization. The interface of ZTAp/Fe composite, which has been proved to have bearing and transitional capacity by scratch test, was formed by chemical bonding with elemental diffusion, besides mechanical bonding. The metallization mechanism of elemental diffusion can be explained by the migration of glass phase, and the elements diffusion between the interface and iron matrix is to form solid solution. 相似文献
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采用氟盐法制备了TiB2质量分数为3%的原位合成TiB2/6061复合材料,研究了固溶温度和固溶时间对复合材料硬度和耐磨性能的影响。结果表明:TiB2颗粒弥散分布在6061铝合金基体中,明显细化6061铝合金基体晶粒。当固溶温度一定时,随固溶时间延长,复合材料的硬度和耐磨性可获得明显提高,但固溶时间在6~10 h时,复合材料的性能变化不显著。当固溶时间一定时,随固溶温度升高,复合材料硬度和耐磨性呈现先上升后下降的趋势。3wt%TiB2/6061复合材料经530 ℃×10 h固溶处理后,硬度和耐磨性能最佳,相较于铸态硬度值提高了79.5%,磨损量减少了59.1%。固溶处理后复合材料的磨损表面犁沟变细变浅,材料脱落现象减少。 相似文献
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Karolina Mazur Raminder Singh Ralf P. Friedrich Hatice Gen Harald Unterweger Kamila Saasiska Rafa Bogucki Stanisaw Kuciel Iwona Cicha 《大分子材料与工程》2020,305(9)
The composites based on polylactide (PLA) and poly (3‐hydroxybutyrate‐co‐3‐hydroxyvalerate) (PHBV) with the addition of antibacterial particles: silver (Ag) and copper oxide (CuO) are characterized. Basic mechanical properties and biodegradation processes, as well as biocompatibility of materials with human cells are determined. The addition of Ag or CuO to the polymers do not significantly affect their mechanical properties, flammability, or biodegradation rate. However, several differences between the base materials are observed. PLA‐based composites have higher tensile and impact strength values, while PHBV‐based ones have a higher modulus of elasticity, as well as better mechanical properties at elevated temperatures. Concerning biocompatibility, each of the tested materials support the growth of fibroblasts over time, although large differences are observed in the initial cell attachment. The analysis of hydrolytic degradation effects on the structure of materials shows that PHBV degrades much faster than PLA. The results of this study confirm the good potential of the investigated biodegradable polymer composites with antibacterial particles for future biomedical applications. 相似文献
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由于对置受限式撞击流反应器较高的传热及混合效率,能够制备出粒径小、均匀且分布范围窄的超细颗粒。本文采用碘化物-碘酸盐平行竞争反应体系研究入射速度、结构尺寸对对置受限式撞击流反应器微观混合效果的影响规律,并将混合腔尺寸同等比例放大一倍进行对比研究。结果表明,随着入射速度的增大,离集指数减小,微观混合效果提高。喷嘴间距与喷嘴直径比的增大使得离集指数增大,微观混合效果降低。离集指数随着混合腔高度、混合腔出口尺寸的增大呈现先增大后减小的趋势,且混合腔高度对混合效果的影响较混合腔出口尺寸显著。将对置受限式撞击流反应器混合腔尺寸扩大一倍,离集指数增加到原来的2.4倍,微观混合效果显著下降,但是在较大入射速度下,两种结构的混合效果差距减小。研究结果可为纳米复合含能材料的制备提供高效、安全的技术支持。 相似文献
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《Ceramics International》2020,46(14):22661-22673
Characteristics of ZrB2–SiC ultrahigh temperature ceramic matrix composites (UHTCMCs) reinforced with ZrC and carbon fiber (Cf) were investigated in this article. Spark plasma sintering (SPS) process was utilized to fabricate the samples at 1800 °C for 5 min under 30 MPa punch pressure and vacuumed atmosphere. In all samples, the volume ratio of ZrB2: SiC was equal to 4:1, and the summation of ZrC and Cf reinforcements was 7.5 vol% with different ZrC: Cf ratios. Field emission scanning electron microscopy (FE-SEM), energy dispersive spectroscopy (EDS), densitometry, flexural strength, and hardness measurements were employed for characterization of the prepared samples. Microstructural inspection revealed the formation of SiC sheath around the carbon fibers due to several reactions in the surface SiO2 layers existed on the SiC particles. Optimal flexural strength (628.4 MPa) and hardness (20.8 GPa) values were achieved for the sample co-reinforced with 6.5 vol% ZrC and 1 vol% Cf, with a relative density of 97.7%. 相似文献
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High-efficiency filtration in residential forced-air heating, ventilation, and air conditioning (HVAC) systems protects equipment and can reduce exposure to particulate matter. Laboratory tests provide a measure of the nominal efficiency, but they may not accurately reflect the in situ efficiency of the filters because of variations in system conditions and changes in filter performance over time. The primary focus of this paper is to evaluate the effective filtration efficiency, which is inclusive of any loading and system impacts, in 21 occupied residential homes through in-duct concentration measurements. We considered the role of filter media by testing both electret and non-electret media, as well as the role of loading by considering new and used filters. The results show that filters with higher nominal efficiency generally had higher effective filtration efficiency in the same home. In terms of performance change, there is no significant difference in efficiency between initial and 3-month non-electret filters, but the efficiency of electret filters generally decreased over time. However, both nominal efficiency and performance change were vastly overshadowed by the wide variety in loading and system conditions across homes, making it hard to predict filter efficiency in a given home without in situ measurements. 相似文献